The goal of this Third Edition is to update long-term data presented in earlier editions and to generate new syntheses and conclusions about the biogeochemistry of the Hubbard Brook Valley based on these longer-term data. There have been many changes, revelations, and exciting new insights generated from the longer data records. For example, the impact of acid rain peaked during the period of the HBES and is now declining. The longer-term data also posed challenges in that very marked changes in fluxes occurred in some components, such as hydrogen ion and sulfate deposition, calcium and nitrate export in stream water and biomass accumulation, during the almost